This book describes the electrochemical behavior of supramolecular systems. Special emphasis will be given to the electrochemistry of host-guest complexes, monolayer and multilayer assemblies, dendrimers, and other supramolecular assemblies. A fundamental theme throughout the book is to explore the effects that supramolecular structure exerts on the thermodynamics and kinetics of electrochemical reactions. Conversely, attention will be placed to the various ways in which electrochemical or redox conversions can be utilized to control or affect the structure or properties of supramolecular systems. This first book on this topic will be of value for graduate students and advanced researchers in both electrochemistry and supramolecular chemistry.